Organosilicone polymers

ABSTRACT

Organosilicone polymers are provided containing siliconcontaining units A, B and C, where A is SiO4/2, B is a monofunctional siloxy unit in which silicon is bonded to at least one organic moiety bearing an organic-capped poly(oxyalkylene) chain, and C is a monofunctional trihydrocarbylsiloxy unit, and in which there are from about 0.75 to about 2 moles of A, and from about 0.1 to about 1 mole of C, per mole of B. The polymers are useful as surfactants and find particular application in the manufacture of flexible polyester urethane cellular products, including flame-retarded foams.

United States Patent Kanner et al. June 3, 1975 [54] ORGANOSILICONE POLYMERS 3,793,360 2/!974 Prokai et al 5626014482 B '7 Inventors: Bernard n y c e 3,.96,676 3/l974 Kanner et a] 0/448.2 B X Proltai, Mahopac, both of N.Y.; Waller Rosamund, Englewood- Primary Examiner-Paul F. Shaver Attorney, Agent, or FirmM. Klosty (73] Assignee: Union Carbide Corporation, New

York, NY.

221 Filed: July 26, 1973 [571 ABSTRACT PP 382,363 Organosilicone polymers are provided containing sili- Related U S Applicafinn Dma con-containing units A, B and C, where A is SiO B 62 is a monofunctional siloxy unit in which silicon is l 1 33 32252 Sept bonded to at least one organic moiety bearing an organic-capped poly(oxyalkylene) chain, and C is a monofunctional trihydrocarbylsiloxy unit, and in [52] B260/25 which there are from about 0.75 to about 2 moles of [5 H In Cl 7/08 7H0 L A, and from about 0.1 to about 1 mole of C, per mole of B. The polymers are useful as surfactants and find [58] Field 0fSearch"'260/448'2 particular application in the manufacture of flexible polyester urethane cellular products, including flame- [56] Reierences Cited retarded fOams' UNITED STATES PATENTS 26 Claims No Drawings 3,480,583 ll/l969 Bailey et al, 260/4482 B X ()RGANOSILICUNE POLYMERS This is a division ofapplication Ser. No. 293.4 l 5 filed Sept. 29. W71. now L'S. Pat. No. 3.796.676.

BACKURUl'ND OF THE. INYEN'IION The present invention relates to novel organosilicone polymers. and their use in the manufacture of urethane cellular products. particularly flexible polyester urethane foams including flame-retarded foams It is well known that the urethane linkages of are thanc foams are formed by the exothermic reaction of a polyfunctional isocyanate and a polyfunctional active hydrogen-containing compound in the presence of a catalyst. and that the cellular structure of the foamed product is prmided by gas evolution and expansion during the urethane-forming reaction. In accordance with the one-shot process which is the most widely used industrial technique, direct reaction is effected between all of the raw materials which include the polyisocyanate. the active hydrogeircontaining compound. the catalyst system. blowing agent and surfactant. A maior function of the surfactant is to stabilize the urethane foam. that is, prevent collapse of the foam until the foamed product has developed sufficient gel strength to become self-supporting.

It also is well known that suitable active hydrogencontaining compounds include polyether polyols and polyester polyols. From the standpoint of their chemical structure. therefore, urethanes are usually classified as polyethcr and polyester urethanes, respectively. Cellular urethanes also differ with respect to their physical structure and. from this standpoint. are generally classified as flexible. semi-flexible or rigid foams.

Although certain techniques of urethane manufacture such as the "one-shot process" and certain components of the foam formulation such as the polyisocyanates. amine catalyst and blowing agent. are generally useful. a specific problem associated with the production of a particular type of urethane foam and the solution thereto are often peculiar to the particular chemical and physical structure of the desired foamed prod uct. Thus. a significant development in the production of a polyether foam or a rigid foam. for example. may not be generally applicable to the production of other cellular products. ln particular. the efficacy of the foam stabilizer is usually selective with respect to the formation ofa particular type offoam. For example. although flexible polyester foam was originally made using conventional organic surfactants or emulsifiers, such compounds were not effective for the manufacture of flexible polyether foam. As urethane technology advanced and end-uses increased. it became apparent that certain deficiencies in the quality of flexible polyester foam such as the presence of splits and a non-uniform cell structure were attributable. at least in part. to the organic surfactants employed. However. the mere substitution of the organic surfactants with various polysiloxane-polyoxyalltylene block copolymers which had been used as foam stabilizers with satisfactory re sults in the production ofother types of urethane foams (eg. in the production of polyether urethane foams and certain rigid polyester urethane foams). did not produce completely satisfactory flexible polyester foams. A significant development in polyester foam manufacture was the discovery that a satisfactory combination of uniform cell structure and freedom from splits was achieved by using a particular combination of foam stabilizing ingredients. This latter combination comprises: [a] an anionic organic surfactant that is soluble in the polyester polvol reactant at room temperature and LJPtlhlc of lowering the surface tension of the polyester resin reactant when dissolved therein. and lb) a polysiloxane-polyosyalkylenc block copolymer surfactant characterized by a particular molecular weight (from sun to l'HIUUl. siloxanc content (front l4 to 40 weight percent based on the weight of the co polymer) and oxyethylenc content (at least weight percent based on the total amount of ox)alk \lenc groups in the copolymer]. This particular advance in polyester foam manufacture is described in greater detail in US. Pat. No. 3.594.334.

Another class of organosilicone polymers known to the art are those composed of the following two types of silicon-containing units: l inorganic tetrafuno tional units in which the four valences of silicon are bonded to oxygen (EH0 i. and (2) the monofunctional trimethylsiloxy units. (CHgLgSlOnz. Polymers of this type in which the Sit) (CH;,);,SiO,, mole ratio is from 0.8:l to 10:1 are described as effective stabilizers of flexible polycther urethane foams in Belgian Pat. No. 720.212 and corresponding (anadian Pat. No. 860.995. On the other hand. copolymers composed of the aforesaid SiO and (CH hSiO units are ineffective stabilizers of flexible polyester foam.

Also reported in the prior art (US. Pat. No. 3.5l 1.788) are polymers containing the aforesaid inorganic tetrafunctional units in combination with (CH hSiO units either as the sole type of monofunctional unit or in further combination with a second type of monofunctional unit in which the silicon atom is bonded to two methyl groups and a hydroxylterminated poly(oxyalkylene) chain which is linked to the silicon atom by a divalent trimethylene group. In the polymers of US. Pat. No. 3.511.788. the proportion oftetrato total mono-functional units ranges from l:0.o to 1:1.2. Although the polymers of the aforesaid patent are reported therein as useful frothing agents in the manufacture of polyvinyl chloride plastisol foams and foaming agents for simple organic solvents. they are ineffective stabilizers of flexible polyester foam.

An additional factor which further complicates this area of technology is the need to minimize and ultimately overcome the major drawback of urethane foams which is their ability to ignite readily and burn. in view of the fact that urethane foams are used in applications where fire creates a hazard. a great deal of effort has been and is being expended to reduce their flammability. Here too, however. specific types of foams have selective requirements. Flame-retardancy is particularly difficult in the area of flexible foam manufacture in view of the delicate open cell nature of flexible foams as compared with the more highly crosslinkcd and closed-cell rigid foams. The problem is compounded by the desirability of achieving fire-retardant properties without substantial sacrifice of foam quality required for a particular end-use application.

It is an object of this invention to provide new and useful organosilicone polymers which have particular application in the manufacture of cellular polyesterbased polyurethanes.

Another object is to provide particular organosilicone polymers containing inorganic. tetrafunctional silicon-containing units as one type of monomeric unit.

which polymers are effectite stabili7crs of flexible polyester-based urethane foam including llaine retarded foam, and a method for the preparation of said polymers A further ooit-ct is to prmide particular llcublc polyester-based urethane cellular products of reduced flammability. and a process for the manufacture thereof.

Various other objects and advantages of this invention will become apparent to those skilled in the art from the accompanying description and disclosure.

SUMMARY OF THE INVENTION In accordance with one aspect ofthe teachings ofthis invention, organosilicone polymers are provided which contain as essentially the sole types of monomeric units: (A) inorganic tetrafunctional siliconcontaining units in which the four valences of the respective silicon atoms are satisfied by bonds to oxygen, (B) monofunctional polyethensubstituted siloxy units in which silicon is bonded to at least one organic moiety bearing an organiocapped poly(oxyalkylene) chain, and (C) monofunctional trihydrocarbylsiloxy units, and in which the mole ratio of said tetrafunctional to said monofunctional polyether-substituted units is from about 0.75:l to about 2:1 and the mole ratio of said monofunctional trihydrocarbyl to said monofunctional polyether-substituted units is from about 0.1:l to about lil.

For convenience, the aforesaid units of the polymers of this invention are referred to herein generally as the A, B and C units. respectively.

In accordance with a second aspect ofthe present invention, a process for producing flexible polyester based polyurethane foam is provided which comprises reacting and foaming a reaction mixture of: (1 a polyester polyol reactant containing an average of at least two hydroxyl groups per molecule; (2) a polyisocya nate reactant containing at least two isocyanato groups per molecule; (3) a blowing agent; (4) a catalyst comprising an amine; and (5) the organosilicone polymers of this invention comprising the aforesaid tetrafunctional. poIyether-substituted monofunctional and trihydrocarbylsubstituted monofunctional siliconcontaining units A, B and C, respectively. In addition to their efficacy as stabilizers of polyesterbased urethane foams, the organosilicone polymers of this invention possess the further advantageous property of allowing for the formation of flame-retarded foams of acceptable overall quality. In accordance with this aspect of the present invention, flame-retarded flexible polyester-based urethane foams are provided by reacting and foaming reaction mixtures which also include a silicon free, flame-retarding agent.

In providing either non flame-retarded or flameretarded foams, the organosilicone polymers described herein can be introduced to the foam-producing reac tion mixtures either as such, as a blend with various organic additives, or as a component of an aqueous premixture which also comprises the catalyst for the poly ester polyol/polyisocyanate reaction.

The present invention also relates to methods for the preparation of the novel organosilicone polymers described herein, particular solution compositions thereof. and to the foams which are made therewith.

Di MRIIIION ()l lHi" PRliFl'iRRliD EMBUDIlvIbN'IS The functionality of the rcspccthe types of structural 5 units i A. Ii and L'l f the polymers of this IINCI'IUUII defines the number of mygen atoms to which the silicon atom (Si ofany particular unit is bonded. Since each oxygen atom is shared by a silicon atom (Si') of am other unit, functionality also denotes the number of linkages by which the particular unit can be bonded to another portion of the polymer through Si-O-Si'- bonds. Accordingly, in expressing the structural and empirical formulas of the respective units of the polymers of this invention, fractional subscripts are used in which the value of the numerator defines functionality (i.e., the number of oxygen atoms associated with the silicon atom of the particular unit), and the denominator. which in each instance is 2. denotes that each oxygen atom is shared with another silicon atom.

Thus, in the inorganic tetrafunctional units (A) of the polymers of this invention, each of the four valences of silicon is associated with oxygen as shown by the struc ture,

and expressed by the empirical formula, SiO which in abbreviated form is often expressed simply as SiO In monofunctional structural units B of the polymers of this invention, one valence of the tetravalent silicon atom is associated with oxygen and at least one valence is satisfied by a bond to a carbon atom of an organic moiety bearing an organic-capped poly(oxyalkylene) chain. For the sake of brevity, the said organic-capped poly(oxyalkylene) chain-bearing organic moiety is also referred to herein as the polyether group" and is designated herein by the sysmbol E. The remaining valences of silicon of the B units are satisfied by bonds to respective carbon atoms of either two additional polyether groups (E) or two monovalent hydrocarbon radicals, designated herein by the symbol R," or a combination of the E and R groups. Consistent with this definition, the polyether-substituted monofunctional siloxy units (B) of the polymers of this invention have the following general structural formula:

rt -s10 H1 (3) wherein E is the aforesaid organic-capped (poly)oxyalkylene) chain-bearing organic moiety (i.e., a polyether group), R is a monovalent hydrocarbon radical, e is an integer having a value of from I to 3, fhas a value of from O to 2, and the sum e+f is 3.

It is to be understood that the organosilicone polymers of this invention may contain any one of the three types of monofunctional structures encompassed by Formula B [that is, (E)(RJ- SiO,,- (l:')- (l l)Si(),, or E SiO as essentially the sole type of 8 units, or the polymers may contain any combination thereof such as, for example, a combination of (E)(R) Si0,, and )2( |/2- In the monofunctional trihydrocarbylsiloxy units (CI of the polymers of this invention, one valence of silicon is associated with oxygen and each of the remaining three valences is satisfied by a bond to a carbon atom of a monovalent hydrocarbon group, designated herein as R", as shown by the general structural formula,

which has the empirical formula, R SiO,, Within any particular R SiO unit, or, as between different R SiO,, units, the R groups may be the same or dif ferent.

In view of their monofunctionality, the B and C units of the polymers of this invention cannot extend the polymer network since they are chain-terminating groups. This is in contrast to the reactivity of the polyether-substituted diand tri-functional monomeric B 'units of the organosilicone polymers described and claimed in copending application Ser. No. 132,360 filed Apr. 8, I971, of Bela Prokai and Bernard Kanner, now U.S. Pat. No. 3,793,360.1n view of their polyfunctionality, the B units of the polymers of the aforesaid application are chain-extending or polymer-building monomeric units.

The essential polyether group (E) of the monofunctional siloxy units encompassed by Formula B above, are more specifically defined by the formula, WO(C,,H ,,O) L, wherein WO(C,,H ,.O),, is an organic end-blocked poly(oxyalkylene) chain and L is a bivalent organic radical that links the poly- (oxyalkylene) chain, (C,,H ,,O) to silicon. When this more specific expression is used in Formula B above in place of E, the following more detailed definition of the monofunctional siloxy units (B) of the polymers of this invention is provided,

wherein, as above defined, 2 has a value of from 1 to 3,fhas a value of from O to 2, the sum e+f is 3, and R is a monovalent hydrocarbon radical. In the poly(oxyalkylene) chain, (C,,H ,,O),,, d is a number having an average value of from about 4 to about 30, and n can have a value of from 2 to 4 provided at least 75 weight per cent of the poly(oxyalkylene) chain is constituted of oxyethylene units, (C H,O)-. Usually, the average value ofd is from about 5 to about 15, and the average value ofn is from 2 to 2.25. The other oxyalkylene units with which the oxyethylene groups may be in conbination are oxypropylene, --(C H O). and oxybutylene, (C,H O), units. When the oxyethylene units are present in combination with other oxyalkyL ene units, the units of different ty pes can be randomly distributed throughout the poly(oxyalkylene) chain or they can be grouped in TCSPCCIHC subblocl\s. pro\ ided the total average content of (C H,O) in the chain is at least weight percent. Preferably, the total average poly(oxyethylenc) content of the chain. (C,,H- ,,,O),,, is from about to about I00 weight percent.

The bivalent organic groups represented by L in the above Formula B-l can be any of a variety of radicals having from 2 to 14 carbon atoms and are usually hydrocarbon groups. Illustrative are such groups as:

and the like, wherein R, in each instance, is a bivalent branched or straight chain alkylene radical having the formula, C,,,H m being an integer having a preferred value of from 2 to 4, of which 3 is particularly preferred, and R" in each instance is an arylene group having from 6 to 14 carbon atoms, including alkylsubstituted arylene groups. Typical examples of the linking groups (L) are: ethylene (CH CH trimethylene (CH CH CH propylene [CH CH(CH tetramethylene; methylpropylene [-CH CH(CH )CH2]; ethylethylene [-CH CH(C H phenylene (C H tolylene [(CH C H biphenylene (C,,H,-C,,H,); CBH4CH2C;H4 C6H4C(CH3)2C6H4; and the like.

As is evident from the above-described classes of bivalent linking radicals (L- the unsatisfied valences thereof are associated with carbon and thus form a carbon-to-oxygen bond with the poly-oxyalkylene) chain and a carbon-to-silicon bond with the silicon atom of the respective siloxy units.

As further indicated by the above Formula 8-], the poly(oxyalkylene) chain, (C,,H ,,O) is terminated by the organic group, WO-, wherein W is a monovalent organic capping group. lllustrative of the organic caps encompassed by W are such groups as:

RNHC(O), and

RC(O) wherein R, in each instance, is a monovalent hydrocarbon radical having from I to l2 carbon atoms, and is usually free of aliphatic unsaturation. The groups (WO) which end-block the poly(oxyalkylene) chains are, therefore, corresponding RO, RNHC(O)O and RC(O)O- monovalent organic radicals. in the aforesaid capping (W) and terminal (WO) groups, R can be any of the following: an alkyl group includ' ing linear and branched chain alkyl groups having the formula, C,,H wherein y is an integer of from 1 to 12, such as, for example, methyl, ethyl, n-propyl, isopropyl, n-buty], t-butyl, octyl and dodecyl groups; a cycloaliphatic radical including monocyclic and bicyclic groups such as, for example, cyclopentyl, cyclohexyl and bicyclo[2.2.l]heptyl groups; an aromatically unsaturated group including aryl, alkaryl and aralkyl radicals such as, for example, phenyl, naphthyl, xylyl, tolyl, curnenyl, mesityl, t-butylphenyl, benzyl, betaphenylcthyl and l-phenylpropyl groups; alkyl and aryl substituted cycloaliphatic radicals such as. for example. methylcyclopentyl and phenylcyclohexyl radicals, and the like. It is evident. therefore. that the terminal group [W of the essential polyethcr group (E) of the monofunctional siloxy units (B) ofthe polymers of this inwntion. as well as the terminal groups of additional polyether groups E) which may or may not be present. can be corresponding alko\y. aryloty. aralkosy. alkaryloxy. C \Cl0Ltll\'OX acyloxy. aryi-C(()l()-. alkyl carbamate and aryl carbamatc groups.

The generally preferred R groups are phcnyl. louei alkyl radicals. the lower alkyd-substituted aryl groups and the aryl-substituted lower alkyl groups. wherein the term lower alkyl" denotes C C alltyl radicals Thcrc fore. illustrative of the preferred capping groups represented by W of the above Formula B1 are: methyl. ethyl. propyl. butyl. phenyl. benzyl. phenylethyl (CnHn-C:Hql. acetyl. benzoyl. methylcarbamyl [CH NHC(O)]. cthylcarbamyl llC H.-,NHC(O)]. propyl and butyl-carbamyl groups. phenylcarbamyl [C..H,.l\'HCtOl-l. tolylearbamyl [((H MC H NHC(O)I. benzylcarbamyl [C H -.CH NHC(O)-]. and the like.

It is to be understood that the terminal organic radical (WO) of the respective polyether groups of the polymers of this invention may be the same throughout the polymer or may differ as between the B units. Likewise. the WO. radical may also be the same or different within any particular unit containing more than one polyether group such as the (E) (R)SiO,, and (E):;Si- O units encompassed by Formula B-l above. For example, the polymer compositions of this invention can contain polye'ther groups in which the terminal group (WO) is benzyloxy (C H CH O-) and other polyether groups in which WO is a hydrocarbylcarbamate group such as methylcarbamate. CH;,NHC(O )O--. or an aeyloxy group such as acetoxy.

The preferred B units of the polymers of this invention are those in which one polyether group (El is bonded to silicon and the remaining two valences of silicon are bonded to monovalent hydrocarbon groups. designated hereinabove as R. Thus. when in Formula B-l. u is l and fis 2. the B units have the preferred structure:

wherein W. tC,,H ,,O),,- and -L- are as defined with specific reference to Formula B-l. As also described above. monovalent hydrocarbon groups. desig nated as R". are bonded to silicon of the monofunctional siloxy units (C) as defined by general formula C above. The monovalent hydrocarbon groups represented by R and R are free of aliphatic unsaturation and contain from I to 12 carbon atoms, and can be any of the following: an alkyl group including linear and branched chain alkyl groups encompassed by the formula. C H wherein y is an integer from I to [2; a cyeloaliphatie radical including monocyclic and bicyclic groups; an aromatically unsaturated group including aryl. alkaryl and aralkyl radicals; and other combinations of the aforesaid groups such as alkyl and ary lsubstituted cycloaliphatic radicals; and the like.

Typical of the aforesaid respective classes of R and R are: methyl. ethyl. n-propyl. isopropyl. n-butyl. t butyl. ictyl and decyl groups; cyclopentyl. cyclohexyl and bieyclollll Iheptyl groups; phenyl and naphthyl groups; sylyl. tolyl. cumeiiyl, mesityl and tbutylphenyl groups; benz yl. bcta-phenylethyl and lphenylpropyl groups. triethylcwlopentyl and phenylcyclohexyl'. and the like.

()f the alkyl groups represented by R and R. the lower alkyl groups having from l to 4 carbon atoms arc preferred of which methyl is especially suitable, It is to be understood that within any one of the monofuuc tional trihydrocarbylsiloxy C units. R,.Si() the R groups may he the same or different and that. as between such units, the R groups may also be the same or different. Similarly. as between the preferred monofunctional siloxy 8 units. (E](R]- .SiO of the polymers of this invention. the respective R groups may be the same or different and may or may not be the same as the R groups of the monofunctional C units. lit the most preferred polymers of this invention. the polyether-substituted monofunctional siloxy units (8) are of the (E)(R) SiO type. and essentially all of the R and R groups bonded to the silicon atoms are methyl groups.

The novel organosilicone polymers of this invention are depicted by the general expression.

in which the recurring monomeric units A are SiO and the B and C units are as described above with specific reference to Formulas B and C When these respective definitions of the A. B and C units are included in the above expression. the polymeric compositions of this invention are expressed as follows:

wherein: E represents a polyether group having the formula. WO(C,,H ,,O).,L, in which WO is an organic terminal group of the poly(oxyalkylenel chain. -(C,,H ,,Ol, and L is a bivalent hydrocarbon radical that links the chain to silicon. as defined above with particular reference to Formula B-1; and. as also previously defined, R and W are monovalent hydrocarbon groups. e has a value of from 1 to 3 and f has a value of from 0 to 2, provided the sum e+f is 3; and the relative proportions of monomeric units A, B and C. expressed on a mole basis. are defined by the relative values of a. b and a. respectively. The polymers of this invention contain from about 0.75 to about 2 moles of A per mole of B. and from about 0.l to about 1 mole of C per mole of B. Therefore. in the above expressions D and D-l. the ratio of cub is from about 0.75:] to about 2:l. and the ratio of (:b is from about 0.1:1 to about l3].

The polymers of this invention have a total polyether content of from about 50 to about 85 weight per cent and a corresponding total siloxane content of from about 50 to about l weight percent, the said polyether and siloxane contents being based on the combined based on the combined total weight ot the monomeric units.

The polymers of this invention are generally useful as surfactants and include compositions which find partictotal weight of the monomeric units A. B and (1 As 5 ular application in the manufacture of polyester ure used herein. the expression "total polyether content thane foam. including flame-retarded foam. Of the denotes the sum of the combined total weights of the novel polymeric surfactants described herein. a getterpolyether groups [El that are bonded to silicon of the ally preferred class. particularly for use in the formamonofunctional siloxy units 8. Accordingly. the cv tion of flexible polyester urethane foam. are the polypression total siloxane content" denotes the sum of It] mers represented by the following expression: the combined total weights of: t l t the SiO units. [2) the monofunctional B units less the total weight of the polyethcr groups (E), and (3) the monofunctional units [510 1 1 [WO-(C H O) -C l-l -SiO The organosilicone polymers of this imention can l5 contain the tetrafunctional A units a: monofunctional [3 $10 D-9 x I 4 3 1/2 c C units in combination with one or more of the various types ofB units encompassesd by the above Formula 8. wherein: W is as aforesaid; R and R are lower alkyl as illu lratfid y hL following radicals having I to 4 carbon atoms; the link between wherein: E. R and R have the aforesaid significance; l, H and are positive numbers. the respective sums v+w and v+w+.\ being equal to h; the mole ratio of the SiO units to total polyether-substituted siloxy units to total trihydrocarbylsiloxy units (that is, the mole ratio of the [A]:[Bl: [C] units. respectively! is defined by ushst' in which latter ratio the values of a, h and c are as aforesaid (that is. u is from about 0.75 to about 2, b is l, and is from about (ll to about l); and the total polyether content is maintained within the aforesaid range of from about to about 85 weight percent.

ter-based urethane foam are those depicted by the following expression:

wherein d, m and a:b:c' are as defined with respect to D-9, and R is phenyl, lower alkyl, lower alkaryl or aryl-substituted lower alkyl groups.

In the preparation of the organosilicone polymers of this invention, silicon-containing reactants, designated herein as reactants A, B and C, are employed in which silicon is bonded directly to hydrolyzable groups the number of which corresponds to the number of oxygen atoms bonded to silicon of the respective monomeric units A, B and C. The hydrolyzable groups can be halogen or organic radicals bonded to silicon through an oxygen atom including any combination thereof. Illustrative of suitable reactants (A') from which the tetrafunctional monomeric units (A) are derived are those encompassed by the general formula:

X Si(OY) (OCOY),

(A) wherein: X is halogen (usually chlorine or bromine); Y is a hydrocarbon radical such as alkyl, aryl and aralkyl, and the like; and p, q and r can each have a value of zero to 4, provided the sum p-l-q+r is four. Typical examples of this reactant are silicon tetrachloride, lower alkyl orthosilicates having the formula, Si(OY') wherein q is 4, and the lower alkyl partial esters of silicon tetrachloride, (Cl),,Si(OCOY'),, wherein each of p and 1' has a value of from l to 3, provided p+r is 4, and Y in each instance is an alkyl group having from 1 to 4 carbon atoms. Tetraethoxysilane (also known as tetraethyl orthosilicate or simply as ethyl orthosilicate) is especially suitable as the A reactant.

REactant B which is the ultimate source of the polyether-substituted monofunctional B units contains one hydrolyzable group bonded to silicon, and encompasses compounds having the general formula:

wherein: R corresponds to the monovalent hydrocarbon group (R) of the polyether-substituted monofunctional B units encompassed by general Formula B above; E is either hydrogen or the polyether group (B) of general Formula 8 above, having the more specific structure, WO(C,,H ,,O), L, wherein the bivalent linking group (L) is preferably an alkylene group, -C,,,H as defined above with reference to Formula B- l: e and falso have the same significance as in the monofunctional B units (that is, e is from I to 3,)" is from to 2, and the sum e-l-f is 3); and Z is one of the aforesaid hydrolyzable groups, X, OY or OCOY wherein X and Y are as defined with respect to reactant A.

Illustrative of the various types of reactants encompassed by Formula B' are the following:

E SiZ wherein: R and the preferred organic-capped polyether group, WO(C,,H ,,O),,C,,,H2m, are as above defined with specific reference to Formula B-l; X is halogen (usually chlorine); and Y is usually a lower alkyl group (Y') such as methyl or ethyl. In the preparation of organosilicone polymers of this invention in which a combination of different polyether-substituted units B are present, such as the (E)(R) SiO and (E) (R)SiO,, units, more than one B reactant is required. For example, in preparing the polymers illustrated above by expression D-S, the respective polyether-substituted monofunctional siloxy units are obtained by employing a combination of corresponding B reactants such as the aforesaid B'-l and B'-4. Alternatively, such polymers are provided by employing a combination of hydrosilanes such as reactants B-6 and B'7, as the source of the siloxane portions of the respective B units, and the silicon-bonded hydrogen is subsequently replaced by the polyether groups (E), as described hereinbelow. It is to be understood that a combination of polyether-substituted and hydrogensubstituted reactants such as B-l and B-7 can also be employed without departing from the scope of this invention.

Reactant C which is the source of the monofunctional trihydrocarbylsiloxy units (C) of the polymers of this invention, also contains one hydrolyzable group and is represented by the following general formula:

wherein: R corresponds to the monovalent hydrocarbon group (R) of the monofunctional C units encompassed by Formula C above; Z can be any of the aforesaid hydrolyzable groups, designated as X. OY and -OC(O)Y, and can additionally be a hydroxyl group, or an OSiR: group in which event the C reactant is a disiloxane.

Illustrative of the various types of reactants encompassed by Formula C. which may be used alone or in combination, are the following:

wherein: R is as defined hereinabove; X is halogen (usually chlorine); and Y is usually a lower alkyl group (Y') such as methyl or ethyl.

THe organosilicone polymers of this invention are produced by the process which comprises cohydrolyzing the above-described reactants A, B and C and cocondensing the hydrolyzate, thereby providing either the polymer compositions of the invention as the direct product of the cohydrolysis-cocondensation reaction, or an intermediate polysiloxane polymer product containing silicon-bonded hydrogen which is reacted further to substitute silanic hydrogen with polyether groups. Reactants A, B and C are employed in respective amounts selected to provide the corresponding monomeric A, B and C units in the relative molar proportions defined above as the a:b:c ratio in which ratio the values ofa and c are from about 0.75 to about 2 and from about ().l to about 1, respectively, expressed on the normalized basis of b=l. Accordingly, in producing the polymers of this inventioh, from about 0.75 to about 2 moles of reactant A are employed per mole of reactant B and from about 0.1 to about 1 mole of reactant C are employed per mole of B. Water is preferably used in an amount at least sufficiently to satisfy the stoichiometry of the cohydrolysis reaction. Usually, water is used in a l() to 200 percent molar excess of the stoichiometric requirements, although more than a 200 percent molar excess can be employed without departing from the scope of this embodiment of the present invention.

The cohydrolysis-cocondensation reaction for producing the novel polymers described herein is illustrated by the following equation l wherein for convenience, tetraethoxysilane is shown as reactant A, and chlorine is shown as the respective hydrolyzable groups of reactants B and C:

Egggion 1,:

wherein, as above-defined, E is either hydrogen or a polyether group (E); R and R are monovalent hydrocarbon groups; 2 is from 1 to 3 andfis from 0 to 2. provided e+fis 310', b and c which represent the number of moles of the indicated A, B and C reactants. can be any positive numbers provided the ratio thereof, that is, a;b':c, when expressed on the normalized basis of b=l, is about 0.75-221:0.1-1, thereby providing polymers in which the respective monomeric units A, B and C are present in corresponding molar proportions, the a:b:c ratio, when expressed on the normalized basis of b=l also being about 0.75-221:0.l-l. Provided the ratio of the number of moles of reactants employed is as specified, the actual number of moles employed (and thus the quantity of polymer produced) can be any multiple of the a':b':c ratio, depending upon the scale on which it is desired to carry out the reaction.

When the B reactant employed in the cohydrolysiscocondensation reaction of equation (1) is a hydrosilane (such as, for example, reactants B'-6 to B'-8 above), the product is reacted further with a monoolefinic poly(oxyalkylene) ether having the formula, WO--(C,,H,,,O) -C,,,H In the ether reactant, the moiety, WO(C,,H ,,O) is as above-defined with respect to the corresponding organic terminated poly- (oxyalkylene) chain of the polyethensubstituted siloxy units (B), and C,,,H is a monovalent olefinic group wherein m has the same significance as in the bivalent alkylene group (C,,,H,,,,) of the polyether substituents (E) of monomeric units B (that is, m has a value of from 2 to l4. and is usually from 2 to 4). This embodiment of the method for producing the novel polymers of the present invention is illustrated by the reactions of the following equations (2) and (3) wherein tetraethoxysilane and a trihydrocarbylmona chlorosilane typically illustrate the A and C reactants, respectively, the B reactant is shown as a dihydrocarbylmonochlorohydrosilane, and, for the purpose of illustration, the A, B and C' reactants are used in equimolar proportions:

mam1= Eggtion 3:

Since the reaction of equation (2) is illustrated on the monolpolyether)-substituted dihydrocarbylmonobasis otcquimolar amounts of reactants A. B and C chlorosilane. C is illustrated as a trihydrocarbylmonothe mole ratio of (JJhK' in equations (2] and (3) is. of chlorosilane. and reactants A. B and C are employed course. 1:111. When reactant B contains more than in equimolar amounts:

Egggtion 4:

+ a c n on 2 am one silicon-bonded hydrogen atom as in reactant B'-7 above, for example, the intermediate product of the rewherein R. R". W, n, d and m are as previously defined 35 herein and the mole ratio (a.'b:c) of the respective siliaction of equation (2), is reacted with at least a correcon-containing units is about l:l:]. sponding number of moles of the monoolefinic poly- Reactants B encompassed by Formula B above in ether reactant to satisfy stoichiometric requirements. which fmm 0116 to thr polye h r group bonded to silicon, are in turn prepared by reacting the In accordance allow embodiment of the 40 aforesaid monoolefinic poly(oxyalkylene) ethers.

cess for preparing the novel organosilicone polymers of W() (CHHHO) C'H2m h with hydrosilanes in lm'emlon' B reacmht is one in which E0 of the which the number of silicon-bonded hydrogen atoms above Formula is Polyelher g p (E) rather than corresponds to the number of polyether groups desired hydrogen and the P y are Produced as the direct in the monomeric B units. For example, the B reactant product of the cohydrolysis-cocondensation reaction. 45 shown in equation (4) above which is of the (E)(R)- This embodiment is illustrated by the reaction of the ,SiCl type as well as the B reactants ofthe (E) (R)SiCl following equation (4) wherein tetraethoxysilane typiand (E SiCl types, are prepared as illustrated by equacally illustrates the A reactant, B is shown as a tions (5)t7) below.

Egungion {wo- (c u o) -c 1i 1 5101 wherein: R, W, n, d and m have the previously defined significance, and the monoolefinic group, C,,,H is preferably vinyl, allyl or methallyl, the allyl group being especially suitable. The monoolefinic polyether reactants used in the reactions of equations (3) and (5)-(7) above, can be prepared by starting alkylene oxide polymerization with a monoolefinic alcohol such as allyl alcohol to provide HO-(C,,H ,,O) C,,,H (wherein n and d are as previously defined herein and m has a value of at least 3), followed by capping of the terminal hydroxyl group with the aforesaid organic radical, W-, such as methyl, phenyl, benzyl, acetyl, methylcarbamyl and like capping groups. Further details concerning the method of preparation of such polyether reactants are described in British patent specifcation Nos. 1,220,47l and 1,220,472. Alternatively, the polyether reactants can be prepared by starting the alkylene oxide polymerization with an alkanol such as methanol, an aralkyl alcohol such as benzyl alcohol, a phenol and the like, followed by capping of the terminal hydroxyl group of the reaction product with the monoolefinic group such as vinyl, allyl, methallyl and the like. Of these various polyether reactants, allyl alcohol-started poly(oxyalkylene) ethers are especially suitable.

The addition of the silanic hydrogen of the respective hydride reactants of equations (5)-(7), as well as the addition of silicon-bonded hydrogen of the intermediate polymer product shown in equation (3), to the monoolefinic group, C,,,H (e.g., CH- CH=CH of the polyether reactant, are platinumcatalyzed reactions. Usually, platinum is used in the form of chloroplatinic acid in a catalytic amount such as from 5 to 150 parts per million parts by weight, based on the combined weight of the silicon-containing and polyether reactants. Suitable reaction temperatures range from about room temperature (25C.) to about l50C. If desired, the hydrosilation reactions may be conducted in the presence of liquid aromatic hydrocarbons such as toluene and xylene, although other non reactive solvents can also be used.

When the organic radical (W) of the terminal group (WO) of the poly(oxyalkylene) chain of the polyether-substituted monofunctional units (B) is a monovalent hydrocarbon group (that is, the abovedefined R- group such as methyl, phenyl and benzyl groups, the polymers are preferably prepared in accordance with the method illustrated by the reaction of equation (4) above, in which the B reactant already contains the polyether group (E) and the polymer is the direct product of the cohydrolysis-cocondensation reaction. When the organic cap (W) of the polyether group of the B units is an acyl (RCO) or carbamyl (RNHCO) group, it is usually preferred to prepare the polymers of this invention in accordance with the reactions of equations (2) and (3) whereby, as shown, the polyether groups (E) are introduced in a step subsequent to the cohydrolysis-cocondensation reaction.

The above-described cohydrolysis-cocondensation reactions for producing the organosilicone polymers of this invention can be carried out at temperatures from about 25C. to about l50C., in the presence or absence of a solvent or diluent. The presence of solvents may aid by increasing compatibility between reactants, effecting distribution, and thereby avoiding gel formation and controlling reaction rates. Useful solvents are aromatic hydrocarbons (such as, for example, toluene and xylene), mixtures of aromatic hydrocarbons, low molecular weight alcohols (such as. for example, isopropanol), ethers including low molecular weight polyethers in which hydroxyl groups initially terminating the chains have been capped with an organic group (such as, for example, methyl) and other solvents which are non reactive with silicon-bonded functional groups (such as SiH, Si-Cl and Si-OY) of the A, B and C reactants.

The byproducts of the cohydrolysis-cocondensation reaction depend, of course, on the nature of the hydrolyzable groups of the A, B' and C reactants, and are readily removed from the polymeric product, usually by fractional distillation. For example, the ethanol and hydrochloric acid formed as by-products of the illustrative reactions of equations (1), (2) and (4) above, are readily removed, together with excess water, as a C H OHHCll-l O azetrope. As desired, any organic solvent used in the polymer preparation is also removed by conventional separation techniques to obtain a substantially percent active polymer composition. After removal of by-products and water, a substantially neutral product of the cohydrolysiscocondensation reaction is provided. Although neutralization is usually not necessary, sodium bicarbonate may be added and the polymer product filtered to remove platinum residues introduced during the platinum-catalyzed hydrosilation reactions illustrated by equations (3) and (5) (7) above.

In addition to the A, B and C units, the polymers of this invention may contain residual silanols and residual hydrolyzable groups remaining from the reactants employed in the preparation thereof. In addition, a small percentage (on the average, usually about 10 mole percent or less) of the total polyether groups (E) may be residual, uncapped hydroxyl-terminated groups [that is, HO-(C,,H ,,O) -C,,,H introduced with the monoolefinic poly(oxyalkylene) ether reactants employed in the reaction of equation (3) above, or in the preparation of B reactants as illustrated by the above equations (5)-(7). In the use of the polymers of this invention as stabilizers of polyester foam, the com bined weight of the aforesaid residual groups should be no higher than about lO percent, and is preferably less than 6 weight percent, based on the total weight of the polymer.

The content of such residual groups is substantially reduced and minimized by treatment of the polymeric products with an organic isocyanate in the presence of an amine catalyst such as those described hereinbelow as suitable for the urethane-forming reaction (for ex ample, triethylamine and N-ethylmorpholine), or a metal catalyst such an organo-tin compounds (for example, stannous octoate, dibutyl tin dilaurate, and the like). Usually, the organic isocyanate employed in this treatment is an alkyl, aryl or aralkyl mono-isocyanate, such as, for example, methyl, ethyl, phenyl and benzyl isocyanates. The treatment of the polymer product in this manner may be carried out in the presence or absence of a solvent or diluent. Aromatic hydrocarbons such as xylene and toluene are suitable as the solvent medium.

The polymers of this invention are normally liquid materials and have molecular weights which vary over a relatively wide range. Generally, the average molecular weights of the polymers of this invention range from about 1,000 to about 10,000 (as measured by Gel Permeation Chromatography using a calibration curve based on dimethylsiloxane fluids). The organosilicone polymers of this invention are mixtures of polymer spe cies which differ in molecular weight, polyether and siloxane contents, and relative molar proportions of the monomeric units. It is to be understood, therefore, that as expressed herein, the values of these parameters are average values.

The organosilicone polymers of this invention are effective as stabilizers of flexible polyester urethane foams and can, therefore, be used as such without the need for combination with an anionic or cationic or ganic surfactant, or other type of organic additive. The polymers can be employed as a substantially I percent active stream, or they can be employed in dilute form as a solution in polar solvents (e.g., glycols) or non polar organic solvents such as normally liquid aliphatic and aromatic unsubstituted and halogen substituted hydrocarbons (e.g., heptane, xylene, toluene, chlorobenzenes and the like). In addition to the polymers, the other essential types of components and reactants employed in the production of flexible polyester urethane foam in accordance with the process of this invention are polyester polyols, organic polyisocyanates, amine catalyst and blowing agent. When producing self-extinguishing foams, the foam-producing reaction mixture also contains a flame-retardant. The organosilicone polymers of this invention are usually present in the final foam-producing reaction mixture in amounts of from about 0.15 to about 4.0 parts by weight per I00 parts by weight of the polyester polyol reactant.

It is often the preferred practice of foam manufacturers to premix the foam stabilizer, amine catalyst and water (which is the usual source of at least part of the blowing action), and to feed the aqueous premixture to the foam-producing reaction mixture as a single stream. The mere mixing of the organosilicone polymers of this invention with the catalyst and water, however, forms a heterogeneous mixture which detracts from the processing advantage of adding these compo nents as a combined stream rather than as individual streams. The problem of premix incompatibility is overcome in accordance with the present invention by providing homogeneous aqueous premixtures comprising the organosilicone polymer, amine catalyst, an organic acidic component and, as an additional ingredient, either a water soluble organic surfactant or a water soluble glycol, or both of the latter two types of components. Although these various organic additives can be introduced directly to the aqueous premixture of foam stabilizer and catalyst, the formation of clear, homogeneous aqueous solutions is facilitated by blending the additives with the foam stabilizer (that is, the organosilicone polymers of this invention) and combining the resulting blend with water and the amine catalyst system. In accordance with another embodiment of this invention, therefore, solution compositions are provided comprising the organosilicone polymers of this invention, the aforesaid organic acidic component, and one or both of an organic surfactant and glycol. The organosilicone polymer is present in the solution compositions in an amount of from about 10 to about parts by weight per 100 parts by weight of the solution.

The aforesaid organic acidic component comprises the saturated and unsaturated aliphatic and cycloaliphatic carboxylic acids containing from 15 to 20 carbon atoms. Illustrative of suitable acidic components are the fatty acids such as, for example, palmitic, ste aric, oleic, linoleic, linolenic and ricinoleic acids; resin acids of the abietic and pimaric type; and any combination of the aforesaid acids as well as industrial byproducts and naturally occurring materials comprising such acids. An especially suitable acidic component of the solution compositions and aqueous premixtures of this invention is tall oil which is a by-product of sulfate digestion of wood pulp and is composed largely of fatty acids (oleic, linoleic, linolenic and palmitic acids) and resin acids, and a minor amount of neutral material such as fatty acid esters.

The above-described organic acidic component is present in the solution compositions of this invention in an amount of from about 5 to about parts by weight per parts by weight of organosilicone polymer present in the solution.

The water-soluble organic surfactant which can be a component of the solution compositions of this invention may be of the non ionic, anionic, cationic or amphoteric types, including combinations thereof. Preferably, the organic surfactant is a non ionic surfactant such as: the poly(oxyalkylene) ethers of the higher alcohols having from 10 to 18 carbon atoms including mixtures thereof; polyoxyalkylene ethers of alkylsubstituted phenols in which the alkyl group can have from 6 to 15 carbon atoms; and corresponding polythioalkylene adducts of the aforesaid higher alcohols and phenols. The length of the ether chain is such that appropriate hydrophilic character is provided to balance the hydrophobic portion derived from the alcohol or phenol and render the compound soluble in water. The chain may contain oxyethylene units either as essentially the sole type of unit or oxyethylene in combination with a minor amount of oxypropylene. it is preferred that the hydrophilic portion of the non ionic surfactants be composed essentially of oxyethylene monomeric units. Usually the average number of such -OC H.,-units ranges from about 4 to about 20, although upwards of 40 such units can also be present.

Typical examples of non ionic surfactants which can be used as components of the solution compositions of this invention are the adducts produced by reaction of k moles of ethylene oxide (wherein it has a value of from about 4 to about 40, inclusive of whole and fractional numbers) per mole of any of the following hydrophobes including mixtures thereof: n-undecyl alcohol, myristyl alcohol, lauryl alcohol, trimethyl nonanol, tridecyl alcohol, pentadecyl alcohol, cetyl alcohol, oleyl alcohol, stearyl alcohol, nonylphenol, dodecylphenol, tetradecylphenol, and the like.

Other illustrative water-soluble orga liC surfactants which can be present as a component of the solution compositions of this invention are: sodium, potassium,

ammonium and quaternary ammonium salts of sulfonic acids wherein the hydrocarbyl portion can be alkyl or alkaryl groups containing from to carbon atoms. Examples of such organic surfactants are: sodium tetradecyl sulfonate and sodium dodecylbenzene sulfonate; sodium and potassium salts of sulfonated petroleum fractions such as mineral oil; diethylamine salts of sulfonated C, C alkylated aromatic hydrocarbons; taurine compounds having at least one long chain hydrocarbyl group bonded to nitrogen; and the like.

The solution compositions of this invention may also contain, as a third type of organic component, a glycol of from 2 to about 10 carbon atoms such as, in particular, hexylene glycol (Z-methyLZA-pentanediol), or low molecular weight Carbowax polyethylene glycols.

When both the organic surfactant and glycol components are present in the solution compositions of this invention, the combined concentration thereof ranges from about 5 to about 90 parts by weight per 100 parts by weight of the organosilicone polymer contained therein. When only one of these components is present, the concentration thereof is also within this latter range.

When the aforesaid solution compositions of the organosilicone polymers of this invention are combined with water and amine catalyst such as the catalysts described hereinbelow, clear, homogeneous aqueous solutions are obtained which can be added directly to the foam-producing reaction mixture. From the standpoint of retaining these desirable characteristics of clarity and homogeneity under otherwise adverse ambient temperatures which may be encountered upon standing, storage or shipment prior to use in the foamproducing reaction, the preferred aqueous premixtures are those containing both the organic surfactant (of which non ionics are preferred) and the glycol, in addition to the organic acidic component. It is to be understood that the aforesaid solution compositions of the organosilicone polymers of this invention are also useful when added directly to the final foamproducing reaction mixture rather than being premixed with water and amine catalyst.

The solution compositions of the foam stabilizer as well as the aqueous premixtures of this invention, can contain minor amounts of other ingredients without departing from the scope of this invention. Such components include inhibitors such as for example, d-tartaric acid, tertiary-butyl pyrocatechol and di-tert-butyl-pcresol (lonol"), which reduce any tendency of the foamed product to oxidative or hydrolytic instability. Further, when the foam stabilizers of this invention and/or the amine catalyst are employed as respective solutions, water soluble carrier solvents and components thereof are, of course, introduced into the aqueous premixtures without, however, any deleterious affeet on the effectiveness or homogeneity of the aqueous solution premixtures.

Tl-le relative proportions of the organosilicone foam stabilizer of this invention, the amine catalyst and water in any particular solution are largely dependent upon and determined by the relative proportions of such ingredients which are desired in a particular foamproducing reaction mixture. Accordingly, in the preparation of a particular aqueous premixture of this invention, the relative proportions of the foam stabilizer, amine catalyst and water are adjusted and the aqueous premixture is added to the final foam-producing formulation in an amount sufficient to satisfy the respective functions of such components and to provide a foamed product of desired quality.

The polyester polyols employed in producing flexible foams in accordance with the process of this invention are the reaction products of polyfunctional organic carboxylic acids and polyhydric alcohols. The polyester polyols contain at least two hydroxyl groups per molecule (as alcoholic OH or as OH in COOl-l groups). The functionality of these acids is preferably provided by carboxy groups (COOH) or by both carboxy groups and alcoholic hydroxyl groups. The polyesters can have hydroxyl numbers from 30 to 150, and preferably have hydroxyl numbers from 45 to 65. These hydroxyl numbers are readily determined according to the procedure described by Mitchel et al., ORGANIC ANALYSIS, Volume I (lnterscience, New York I953.

Typical of the polyfunctional organic carboxylic acids that can be employed in producing polyester polyols useful in this invention are: dicarboxylic aliphatic acids such as succinic, adipic, sebacic, azelaic, glutaric, pimelic, malonic and suberic acids; and dicar boxylic aromatic acids such as phthalic acid, terephthalic acid, isophthalic acid and the like. Other polycarbOxylic acids that can be employed are the dimer acids" such as the dimer of linoleic acid. Hydroxylcontaining monocarboxylic acids (such as ricinoleic acid) can also be used. Alternatively, the anhydrides of any of these various acids can be employed in producing the polyester polyols.

The polyhydric alcohols (organic polyols) that can be employed in producing the polyester polyol starting material used in the process of this invention include the monomeric polyhydric alcohols such as, for example: glycerol; 1,2,6-hexanetriol; ethylene glycol; diethylene glycol; trimethylolpropane; trimethyolethane; pentaerythritol; propylene glycol; 1,2-, 1,3- and 1,4- butylene glycols; 1,5-pentanediol, sorbitol; and the like, including mixtures thereof.

Other polyhydric alcohols that can be employed in producing the polyester polyols useful in this invention are the polymeric polyhydric alcohols which include the linear and branched chain polyethers having a plurality of acyclic ether oxygens and at least two alcoholic hydroxyl radicals. Illustrative of such polyether polyols are the poly(oxyalkylene) polyols containing one or more chains of connected oxyalkylene radicals which are prepared by the reaction of one or more alkylene oxides with acyclic and alicyclic polyols. Examples of the poly(oxyalkylene) polyols include the poly- (oxyethylene) glycols prepared by the addition of ethylene oxide to water, ethylene glycol or diethylene glycol; poly(oxypropylene) glycols prepared by the addition of propylene oxide to water, propylene glycol or dipropylene glycol; mixed oxyethylene-oxypropylene polyglycols prepared in a similar manner utilizing a mixture of ethylene oxide and propylene oxide or a sequential addition of ethylene oxide and propylene oxide; and the poly(oxybutylene) glycols and copolymers such as poly(oxyethylene-oxybutylene) glycols and poly (oxypropylene-oxybutylene) glycols. Included in the term "poly(oxybutylene) glycols are polymers of l,2-butyleneoxide and 2,3-butyleneoxide.

lllustrative of further polyester polyol reactants that are useful in producing flexible polyester urethane foam in accordance with the process of this invention are the reaction products of any of the aforesaid polycarboxylic acids and the polyhydric alcohols prepared by the reaction of one or more alkylene oxides such as ethylene oxide, propylene oxide, butylene oxide and mixtures thereof, with any of the following: glycerol; trimethylolpropane; 1,2,6-hexanetriol; pentaerythritol; sorbitol; glycosides such as methyl, ethyl, propyl, butyl and 2-ethylhexyl arabinoside, xyloside, fructoside, glucoside, and rhammoside, sucrose; mononuclear polyhydroxybenzenes such as resorcinol, pyrogallol, phloroglucinol, hydroquinone, 4,6-ditertiarybutylcatechol, and catechol; polynuclear hydroxybenzenes (polynuclear" designating at least two benzene nuclei) such as the di-, triand tetraphenylol compounds in which two to four hydroxybenzene groups are attached either directly by means of single bonds or through an aliphatic hydrocarbon radical containing one to twelve carbon atoms. such compounds being typically illustrated by 2,2-bis(p-hydroxyphenyl)- propane, bis(p-hydroxyphenyl)-methane and the various diphenols and diphenol methanes disclosed in US. Pat. Nos. 2,506,486 and 2,744,882, respectively. Another type of polyester polyol reactant is that produced by reaction of a polycarboxylic acid and the polyether adducts formed by reaction of ethylene oxide, propylene oxide or butylene oxide with phenol-formaldehyde condensation products such as the novolaks.

The organic polyisocyanates that are useful in producing flexible polyester urethane foam in accordance with the process of this invention are organic compounds that contain at least two isocyanato groups. Such compounds are well known in the art of producing polyurethane foams, and are conveniently represented by the general formula:

wherein i is an integer of two or more and Q is an organic radical having the valence of i. Q can be a substituted or unsubstituted hydrocarbon group (e.g., alkylene, cycloalkylene, arylene, alkarylene, aralkylene and the like). can also be a group having the formula Q'-Z'Q' wherein Q is an alkylene or arylene group and Z is a divalent moiety such as O--. OQ- 'O, C(O), S-, -S-Q'--S, or --SO,.

illustrative of suitable organic polyisocyanate reactants are the following including mixtures thereof: 1,2- diisocyanato-ethane; l,3-diisocyanatopropane; 1,4- diisocyanato-butane; l,5-diisocyanatopentane; l,6- diisocyanato-hexane; 1,5-diisocyanato-2,2-dimethylpentane', 1,7-diisocyanato-heptane; 1.5-diisocyanato- 2,2,4-trimethyl-pentane; 1,8-diisocyanato-octane; l,9- diisocyanato-nonane; l,lO-diisocyanato-decane; 1,1 ldiisocyanato-undecane; l l Z-diisocyanato-dodecane; 1,6-diisocyanato-3-methoxy-hexane; l,6-diisocyanato- 3-butoxy-hexane; bis(B-isocyanatopropyl)ether; the bis(3-isocyanato-propyl)ether of 1,4-butylene glycol, (ocNci-ncmcmocrnno; bis(2-isocyanatoethyl) carbonate; l-methyl-2,4-diisocyanatocyclohexane; 1,8- diisocyanato-p-menthane', bis S,6-( 2-isocyanatoethyl bicyclo[2.2.1]-hept-2-ene; bis( 3-isocyanatopropyUsuIfide; bis(isocyanatohexyhsulfide; l,4-phenylene-diisocyanate; 2,4-tolylenediisocyanate; 2,6- tolylene-diisocyanate; crude tolylene diisocyanates; xylylene diisocyanates; 4-chloro-l .3-phenylene= diisocyanate, 4-bromo-1,3-phenylene-diisocyanate; 4 nitro-( 1,3 or l,5)-phenylene-diisocyanate; 4-ethoxy l,3-phenylene-diisocyanate; benzidine diisocyanate toluidine diisocyanate, dianisidine diisocyanate; 2,4

or 4,4'-diisocyanato-diphenyl ether; diphenylmethane- 4,4'-diisocyanate; 4,4'-diisocyanatodibenzyl; isopropyl-benzene-alpha-4 diisocyanate; l,5-diisocyanatonaphthalene; l,8-diisocyanatonaphthalene; 9,10- diisocyanato-anthracene', triphenylmethane-4,4',4"- triisocyanate', 2,4,6-toluene triisocyanate; and many other organic polyisocyanates known to the polyurethane art. in general, the aromatically unsaturated polyisocyanates are preferred.

Also included among the isocyanates useful in the process of this invention are dimers and trimers of isocyanates and diisocyanates and polymeric diisocyanates such as those having the general formula:

in which i andj are integers of two or more, and/or (as additional components in the reaction mixtures) compounds of the general formula:

in which i is one or more and L is a monofunctional or polyfunctional atom or radical. Examples of this type include ethylphosphonic diisocyanate, C H P(O)(- NCO) phenylphosphonic diisocyanate, C H P(O)(- NCO) compounds containing an Si-NCO group, isocyanates derived from sulfonamides (QSO NCO), cyanic acid, thiocyanic acid, and compounds containing a metal NCO radical such as tributyltin isocyanate.

Also useful in the preparation of the flexible polyester urethane foams of this invention are the polyisocyanates of the aniline-formaldehyde polyaromatic type which are produced by phosgenation of the polyamine obtained by acid-catalyzed condensation of aniline with formaldehyde. Poly(phenylmethylene) polyisocyanates of this type are available commercially under such trade names as PAPl, AFPI, Monclur MR, lsonate 390 P, NCO-120 and NCO-20, These products are low viscosity (50-500 centipoises at 25C.) liquids having average isocyanato functionalities in the range of about 2.25 to about 3.2 or higher, depending upon the specific aniline-to-formaldehyde molar ratio used in the polyaminc preparation.

Other useful polyisocyanates are combinations of diisocyanates with polymeric isocyanates containing more than two isocyanato groups per molecule. lllustrative of such combinations are: a mixture of 2,4- tolylene diisocyanate, 2,6-tolylene diisocyanate and the aforesaid poly(phenylmethylene) polyisocyanates; and a mixture of isomeric tolylene diisocyanates with polymeric tolylene diisocyanates obtained as residues from the manufacture of the diisocyanates.

The polyisocyanate reactant of the foam-producing reaction mixture is generally employed in an amount that provides from about to about 150 percent, usually from about to about l2O percent, of the stoichiometric amount of the isocyanato groups requi ed to react with all of the hydroxyl groups of the polyester polyol reactant and any water present as a blowing agent. That is. the total NCO equivalent to total active hydrogen equivalent is generally within the range of about 0.8 to about 1.50, usually about 0.9 to about li2, equivalents of NCO per equivalent of active hydrogen.

The reaction mixtures employed to produce flexible polyester urethane foam in accordance with the teachings of the present invention also contain a catalyst for accelerating the isocyanate-reactive hydrogen reaction. This component usually comprises a tertiary amine and is typically illustrated by the following: N- methylmorpholine; N-ethylmorpholine; N- octadecylmorpholine (N-cocomorpholine); trimethyL amine; triethylamine; tributylamine; trioctylamine; N,- N,NN'tetramethylethylenediamine; N.N,N',N'-tetramethyl-l,3butanediamine; triethanolamine; N,N- dimethylethanolamine; triisopropanolamine; N- methyldiethanolamine; bis(2-dimethylaminoethyl)ether [i.e.. N,N-dimethyl-2-(2 dimethylaminoethoxy)ethylamine}; hexadecyldimethylamine; N,N-dimethylbenzylamine; triethylenediamine (i.e., l,4- diazabicyclo-[2.2.2]-octane); the formate and other salts of triethylenediamine, oxyalkylene adducts of the amino groups of primary and secondary amines and other such amine catalysts which are well known in the art of flexible polyurethane foam preparation. Although metal-containing catalysts such as stannous octoate are usually employed in the preparation of flexible polyether urethane foam, such metal catalysts are not preferred in the manufacture of flexible polyester foam.

It is to be understood that the aforesaid amines may be used as essentially the sole amine catalyst of the re action mixtures employed in this invention or any combination of two or more such amines may be employed. The amine catalyst may also be introduced into the re action mixture in the form of a solvent solution containing from about to about 80 weight percent of total active catalyst. Suitable carrier solvents of amine catalysts include water-soluble glycols such as diethylene glycol; dipropylene glycol; and 2-methyl-2,4- pentanediol.

The catalyst may also be used in combination with other additives such as any ofthe non ionic organic surfactants described above in connection with the solution compositions of this invention. Examples of non ionics which are especially useful as components of the catalyst solutions are the oxyethylated nonylphenol compounds represented by the general formula CtiH ,.C6H (OC,H ),,OH. wherein k is a number having an average value offrom about 9 up to about or more, including average values ofk which are either whole or fractional numbers such as 9, [0.5, 15 and the like. When used. the non ionic organic surfactant may be present in an amount from about 10 to about 80 weight percent, based on the total weight of the catalyst solution. The catalyst solution may also include minor amounts of polysiloxane-polyoxyalkylene block copolymers and/or the organosilicone polymers of this in vention.

It is to be understood that any of the aforesaid amine catalysts or solutions thereof can be added directly to the foam-producing reaction mixture or they can be added in premixed form with water and the polymeric organosilicone foam stabilizers of this invention. in the latter event, the catalyst is preferably added as a com' ponent of the above-described homogeneous aqueous premixtures of this invention.

THe amine catalyst is present in the final foamproducing reaction mixture in an amount offrom about 0.2 to about 8 parts by weight of active catalyst (that is. the amine exclusive of other components present in solutions thereof) per 100 parts by weight of the polyester polyol reactant.

Foaming can be accomplished by employing a minor amount of a polyurethane blowing agent such as water, in the reaction mixture, the reaction of water and isocyanate generating carbon dioxide blowing agent, or through the use of blowing agents which are vaporized by the cxotherm of the reaction, or by a combination of the two methods. These various methods are known in the art. Thus, in addition to or in place of water, other blowing agents which can be employed in the process of this invention include methylene chloride, liquefied gases which have boiling points below F. and above 60F., or other inert gases such as nitrogen, carbon dioxide added as such, methane, helium and ar gon. Suitable liquefied gases include aliphatic and cycloaliphatic fluorocarbons which vaporize at or below the temperature of the foaming mass. Such gases are at least partially flourinated and may also be otherwise halogenated. Suitable fluorocarbon blowing agents include trichloromonofluoromethane, dichlorodifluoromethane, l,l-dichloro-l-fluoroethane, 1,1,1- trifluoro-2-fluoro-3,3-difluoro'-4,4,4-trifluor0butane, hexafluorocyclobutene and octafluorocyclobutane. Another useful class of blowing agents include thermally unstable compounds which liberate gases upon heating, such as N,N'-dimethyl-N,N'- dinitrosoterephthalamide, and the like. The generally preferred method of foaming for producing flexible foams is the use of water or a combination of water plus a fluorocarbon blowing agent such as trichloromonofluoromethane.

The amount of blowing agent employed in the foaming reaction will vary with factors such as the density that is desired in the foamed product. Usually, however, from about 1 to about 30 parts by weight of the blowing agent per parts by weight of the polyester polyol starting material is preferred.

The organic flame-retardants that can be employed in producing flame-retarded flexible polyester foams in accordance with the teachings of this invention can be chemically combined in one or more of the other materials used (e.g., in the polyester polyol), or they can be discrete chemical compounds added as such to the foam formulation. The flame-retardants preferably contain phosphorus or halogen, or both phosphorus and halogen. Flame-retardants of the discrete chemical compound variety include: 2,2-di(bromomethyl) l,3- propanediol; tris(2-chloroethyl)phosphate [ClCH CH- O) P(O)]; 2,3-dibromopropanol; brominated phthalate ester diols (e.g., from tetrabromophthalic anhydride and propylene oxide); oxypropylated phosphoric acid; polyol phosphites [e.g.. tris- (dipropylene glycol)phosphite]; polyol phosphonates [e.g., bis(dipropylene glycol) hydroxymethane phosphonatel; tris(2,3-dichloropropyl)phosphate; tris(l,3- dichloropropyl)phosphate; tetrabromobisphenol-A; tetrabromophthalic anhydride; tetrachlorophthalic anhydride; chlorendic acid and its anhydride; diallyl chlorendate; 2,4,6-tribromophenol; pentabromophenol; bis(2,3-dibrom0propyDphosphoric acid or salts thereof; tris(1-bromo-3-chlor0isopropyl)phosphate; brominated anilines and dianilines; dipoly(oxytethylene)hydroxymethyl phosphonate; 0,0-diethyl- N,N-bis(2-hydroxyethyllaminomethyl phosphonate; di-poly/(oxypropylene) phenyl phosphonate; di-poly- (oxypropylene) chloromethyl phosphonate; di-poly- (oxypropylene) butyl phosphate; and other flameretardants known to the art. Any of the aforesaid compounds may be used as essentially the sole flameretardant or various combinations thereof may be used.

Those of the above flame-retardants of the discrete chemical compound variety which contain groups reactive with hydroxy or isocyanato groups can be used as reactants in producing the polyester polyols or can be reacted with organic polyisocyanates to produce modifled polyols or polyisocyanates having chemically combined flame-retardant groups. Such modified polyester and polyisocyanates are useful as reactants in the process of this invention. In such cases, due regard must be given to the possible effect of the functionality of the compound on the other properties (e.g., degree of flexibility) of the resulting foam.

The flame retardant can be used in an amount from about I to about parts by weight per 100 parts by weight of the polyester polyol reactant.

If desired, minor amounts of other additional ingredients can be employed for specific purposes in produc ing polyester urethane foams in accordance with the process of this invention. Thus the aforesaid inhibitors such as lonol (which can also be added as components of the aqueous premixed solutions of this invention) can be added directly to the final foam formulations. Similarly, hexylene glycol can be added to the final formulation as a compression set additive, although it can also be introduced as a component of the solution compositions described hereinv Paraffin oil can be added to regulate cell structure so as to coarsen cells and thereby reduce the tendency of the foam to split. Other additives that can be empolyed are dyes or pigments and anti'yellowing agents.

The process described herein for the production of flexible polyester urethane foam, can be carried out in accordance with the prepolymer technique by which the polyester polyol and polyisocyanate are prereacted such that a substantial amount of unreacted isocyanate groups remain. The resulting prepolymer is then combined with the foam stabilizers of this invention, amine catalyst and blowing agent. Usually, however, the process is carried out as a one-shot process in which the polyester polyol and polyisocyanate reactants are independently added to the foam-producing reaction mixture. The foaming and urethane-forming reactions occur without the application of external heat. Often the resulting foam is cured by heating the foam at a temperature between about 100C. and about 150C. for about 10 to about 60 minutes to eliminate any surface tackiness, as desired. It is to be understood that variations in process conditionsand manipulative steps can be used as known in the art. For example, the various ingredients of the reaction mixture can be combined and the foaming reaction mixture poured into a mold, or the various ingredients can be combined and the foaming reaction mixture commenced and completed in a mold.

The relative amounts of the various components reacted in accordance with the above-described process for producing flexible polyester urethane foams are not narrowly critical. The polyester polyol and polyisocyanate, taken together, are present in the foam-producing formulation in a major amount. The relative amounts of these two components is the amount required to produce the urethane structure of the foam and such relative amounts are well known in the art. The source of the blowing action such as water, auxiliary blowing agents, amine catalyst and the organosilicone polymeric foam stabilizers are each present in a minor amount necessary to achieve the function of the component. Thus, the blowing agent is present in a minor amount sufficient to foam the reaction mixture, the amine catalyst is present in a catalytic amount (i.e., an amount sufficient to catalyze the reaction to produce the urethane at a reasonable rate), and the organosilicone polymers of this invention are present in a foamstabilizing amount, that is, in an amount sufficient to stabilize the foam. The preferred amounts of these various components are as given hereinabove.

The flexible polyester urethane foams produced in accordance with this invention can be used in the same areas as conventional flexible polyester urethane foams. For example, they can be used as textile interlin ers, cushioning materials for seating and for packaging delicate objects, and as gasketing materials.

The following examples are offered as illustrative of the present invention and are not to be construed as limitative.

Molecular weights given in the examples for various polymer compositions of this invention, were measured by Gel Permeation Chromatography (abbreviated in the examples as G.P.C.") using a calibration curve showing the relationship between the respective elution volumes established for dimethylsiloxane fluids of different molecular weights and the respective known molecular weights of such fluids. ln establishing the calibration curve, the various dimethylsiloxane fluids were in solution in trichloroethylene solvent. In measuring the molecular weights of the polymers described herein, the elution volume observed for any particular polymer product (in trichloroethylene solvent) was equated with the corresponding elution volume of the calibration curve, and the molecular weight associated with that particular elution volume was assigned as the molecular weight of the polymer product. The use of Ge] Permeation Chromatography for measuring molecular weights is discussed in Polymer Fractionation (ed. Manfred J. R. Cantow, Academic Press, Inc. New York i967), pages 123-173, Chapter B4, entitled, Gel Permeation Chromatography," by K. H. Altgelt and J. C. Moore.

The following Examples l-9 illustrate the preparation of organosilicone polymers of the invention by the cohydrolysis-cocondensation reaction of: tetraethoxysilane as the A reactant; dimethylchlorosilane bearing an organic-capped polyoxyethylene chain linked to the remaining valence of silicon through a trimethylene group, as the B reactant; and trimethylchlorosilane as the C reactant. The B reactant in turn is prepared by the platinum-catalyzed hydrosilation reaction of dimethylchlorohydrosilane [HSi(CH Cl] and allyl alcohol-started polyoxyethylene ethers capped with either methoxy or benzyl groups, that is, polyethers having the respective average formulas, CH O(C l-l,,O),,CH Cl l=CH and C H CH' O-(C H,O), CH CH=CH wherein the average value of d is within the range from about 6.3 to about 7.2. Such polyethers usually contain up to about l0 mole per cent of allyl-endblocked, hydroxyl-terminated polyoxyethyl ene ethers as impurities due to incomplete capping of the terminal hydroxyl groups. For convenience, the polyoxyethylene chains of the respective B reactants and B units of the polymer products shown in Examples l-4, 6 and 8 are expressed as though capping thereof had been complete. In the case of the polyether reac- 29 30 tant employed to provide the B reactant used in Exam grams; 0.8 mole), CH -,0(C,H,O), C pics 5, 7 and 9, residual hydroxyl groups were con- H.,-Si(CH Cl (241.8 grams; 0.5 mole) prepared in verted to acetoxy groups by treatment with acetic anaccordance with paragraph (a) above. and 200 grams hydride, employing the following procedure: An aliyl f yl n willer 3 g am as added 10 this mixalcohol-started, benzyl-capped polyoxyethylene ether lure Over 11 Period of One hour out applying exter- (2,930 grams) was dissolved in 100 ml. f t l f nal heat. After the completion of water addition, the

lowed by sparging [0 remove any water The mixture ECHCiiOIl mixture was heated Up o -90C. and VOlib was heated with acetic h d id 224 grams) at tiles (ethanol-water-HCI azeotrope) were removed by [4000 for 3 hours and was then subjected to Stripping fractional distillation over a period of about 3-4 hours. under vacuum for 5 hours' followed by sparging at 0 The reaction mixture was then cooled, neutralized with mospheric pmssure and o o for 6 hours The prod sodium bicarbonate and filtered. Removal of xylene by uct has an average molecular weight of about 440 and "nary evaporafiml at f 1 mercury P is a mixture of compounds having the formula, sure, afforded a viscous liquid reaction product (278 wO (C2H4O)dCH2CY=CH2, and cumains about 87 grams). The polymer product is designated herein as l5 Surfactant A and, based on the relative molar proporand 13 mole percent ofC5H5CH2O(C2H4O)dCH2CH tions of reactants employed, the mole ratio (a:b:c) of CH2 and rcthe E 5104/2 :CH30-(C2H4O)7 2-C3H6-S 101/2 (CH3)3$101/2 units spectively, wherein the the average value assigned units to d is about 6.6. For convenience, this mixture of contained therein is l.6:l:1. polyethers is referred to in Example 5 as Polyether A.

EXAMPLE 2 EXAMPLE 1 Preparation of Surfactant B a. Preparation of CH O(C H O)-, C The reaction of this example was carried out in sub- H Si(CH Cl stantially the same manner described above with refer- To a three-necked flask equipped with stirrer, therence to Example 1(b), except that: the reaction mixmometer, condenser and dropping funnel there was ture contained 350 ml. of xylene, 0.2 mole (21.7 charged: 400 grams (1.03 mole) of the allyl endgrams) of trimethylchlorosilane, 0.8 mole (386 grams) blocked polyether having an average molecular weight of CH O(C H.,O) -C H Si(CH Cl prepared of 389 and the average compo iti CH substantially as described in accordance with Example CHCH (OC2H4)1 OCH 250 ml. of toluene; and H21) above, and one mole (208.24 grams) of tetraeth- 15 parts per million of Pt added as chloroplatinic acid oxysila and the amount f ater add d thereto was (H P CI Th i t was heated to 60C. a d 94,62 42 grams which includes about 20 weight percent in exgrams (1 mole) of dimethylchlorohydrosilane, H-- cess of stoichiometry. The liquid polymer product (440 Si(CH Cl, was then added at such a rate to maintain g IS designated here"! as suffaflam B basfid the reaction temperature at about 8595C. After the relanve molar Propmtions 0f Teaciants completion of the reaction, that is, when the presence 45 P y the mole ratio 0f the of SiH was no longer indicated, toluene solvent was contained therein is l.25:l:0.25. removed by rotary evaporation to provide 480 grams of liquid product having the average composition, CH O- EXAM 3 [3. Preparation of Surfactant A Preparaticm of Surfactant C The apparatus employed in this example comprised In accordance with this example, a reaction mixture areaction flask equipped with thermometer, condenser was prepared containing 200 ml. of xylene solvent, and take-off head, dropping funnel and stirrer. The re- 83.2 grams (0.40 mole) of tetraethoxysilane, 4.34 action flask was charged with trimethylchlorosilane grams (0.04 mole) of trimethylchlorosilane and [59.7 (54.25 grams; 0.5 mole). tetraethoxysilane (166.67 grams (0.36 mole) of a methoxy-eapped polyether- 31 32 substituted dimethychlorosilane having the average scribed under Example 3 above employing the followcomposition. CH;.O-(C H O) C;,H -Si(CH Cl. ing reactants: (i) 0.6 mole (124.8 grams) of tetraeth Water (19.8 grams) was added to the reaction mixture oxysilane; (ii) 0.3 mole (32.6 grams) of trimethyland the resulting mixture was stirred for about one chlorosilane; (iii) 03 mole I604 grams) ofa mixture hour. After removal of volatiles by distillation over a 5 of polyether-substituted dimethylchlorosilanes having 4-hour period. the reaction mixture was cooled to the average formula. WO-(C-,H O) C C.. neutralized with sodium bicarbonate. filtered H Si(CH Cl, wherein about 87 mole percent of the and stripped of solvent by rotary evaporation. The liqcapping groups (W) are benzyl and about 13 mole peruid polymer product (169 grams) has an average mocent are acetyl. this reactant having been prepared by lecular weight (G.P.C.) of about 2.800. Based on the it) the platinum-catalyzed addition reaction of H- relative molar proportions of reactants employed. the Si(CH;,) Cl to above-described Polyether A; and (iv) mole ratio (asbx') of the 1.65 moles (29.7 grams) of water. After removal ofvolcontained in the liquid polymer product, designated atiles, neutralization and filtration. the liquid reaction herein as Surfactant C, is about l.l:l:0.ll. product was found to have an average molecular weight (G.P.C.) of about 2,900. Based on the relative EXAMPLE 4 molar proportions of reactants employed. the mole Preparation of Surfactant D ratio (a:b:c) of the The reaction of this example was carried out in accordance with substantially the same procedure deabout 2:1:1, and about 87 mole percent of the polyscribed under Example 3 employing the following reacether chains are capped with benzyl groups and the retants: l8.8 grams (0.1733 mole) of trimethylchlorosi maining groups are essentially acetyl; for convenience, lane; 57.74 grams (0.2776 mole) of tetraethoxysilane; this combination of capping groups (W) is expressed 90 grams (0.1735 mole) of a benzyl-capped polyetberhereinafter as C H CH /CH C(O). The polymer prodsubstituted dimethylchlorosilane having an average uct of this example is designated herein as Surfactant molecular weight of about 5 l8.5 and the average com- E. position, C H CH O(C H O),,C H Si(CH Cl, where 40 EXAMPLE 6 the average value ofd is about 6.3, prepared by the hy- Preparation of Surfactant F drosilation of an allyl-started, benzyl-capped polyether The reaction of this example was carried out in acwith HSi(Cl-l )-,Cl, as typically illustrated by the pr0- cordance with substantially the same procedure decedure of Example 1(a) above; and 14.4 grams of wascribed in Example 3 employing the following reacter. The liquid reaction product 106 grams) has an avtants: 45.1 grams (0.2 l68 mole) of tetraethoxysilane; erage molecular weight (G.P.C.) of about 3,000 and is 4.7 grams (0.0433 mole) of trimethylchlorosilane; and designated herein as Surfactant D. Based on the rela- 90 grams (0.1735 mole) of a benzyl-capped polyethertive molar proportions of reactants employed, the mole substituted dimethylchlorosilane having an average ratio (a:b:c) of the molecular weight of about 5 l8.5 and the formula. C H- CH3 I units contained in Surfactant D is about l.6:l:l. CH O(C H.,O) ,C H Si(Cl-l Cl, wherein the average value ofd is about 6.3. After removal of volatiles, neutralization and filtration, the liquid reaction product EXAMPLE 5 was found to have an average molecular weight Preparation of Surfactant E (G.P.C.) of about 3.450. Based on the relative molar The reaction of this example was carried out in acproportions of reactants employed, the mole ratio cordance with substantially the same procedure de- (a:b:c) of the units in the polymer product, designated herein as Surfactant F, is about 1.25:1:0.25.

EXAMPLE 7 Preparation of Surfactant G The reaction of this example was carried out in apparatus comprising a 1-liter, three-necked flask equipped with heating mantle, magnetic stirrer. Vigeraux column and dropping funnel. The reaction mixture contained: 0.065 mole (7.05 grams) of trimethylchlorosilane; 0.262 mole 140 grams) of the benzyl-capped, acetoxyscavenged polyoxyethylene-substituted dimethylchlorosilane described as reactant (iii) in Example above; 0.197 mole (40.9 grams) of tetraethoxysilane; and 200 ml. of xylene. Water was added (1 1.0 grams; 0.613 mole) over a period of 1 hour. After standing overnight at ambient temperature, the reaction mixture was distilled over a period of 4 hours, the head temperature being 138C. The mixture was then cooled to 25C., neutralized with sodium bicarbonate, filtered and solvent removed by rotary evaporation. The liquid polymer product is designated herein as Surfactant G. Based on the relative molar proportions of reactants employed. the mole ratio (a:b:c) of the units in the polymer product. designated herein as Sur fact-ant H, is about l:l:0.25.

EXAMPLE 9 Preparation of Surfactant J The reaction of this example was carried out in substantially the same manner described in Example 7 above employing the following amounts of reactants: 0.262 mole (28.4 grams) of trimethylchlorosilane; 0.262 mole (140 grams) of the benzyl-capped, acetoxyscavenged polyoxyethylene-substituted dimethylchlorosilane described as reactant (iii) of Example 5 above; 0.314 mole (65.4 grams) of tetraethoxysilane; and 0.98 mole (17.6 grams) of water. The liquid reaction product remaining after removal of volatiles, neutralization and filtration is designated herein as Surfactant J. Based on the relative molar proportions of reactants employed, the mole ratio (a:b:c) of the units in Surfactant l is l.2:l:1, the polyoxyethylene chains being primarily benzyl-capped, remaining chains being capped with acetoxy as described with particular reference to Surfactant E of Example 5.

For the purpose of comparison. data are also presented herein based on organosilicone polymers conunits contained in Surfactant G is about 0.75:1:0.25, the polyoxyethylene chains being capped (W) with C H CH /CH C(O), as defined with particular reference to Surfactant E of Example 5.

EXAMPLE 8 taining A, B and C units in relative proportions not within the relative mole proportions defined by the present invention. These comparative polymers are designated herein as Polymers I. I1. 111 and IV. In the preparation of Polymers 1, I1 and 111, the procedure described under Example 1(b) above was substantially followed and the polyether-substituted dimethylchlorosilane reactant employed had the average composition, CH O(C H ,O) -C H Si(CH l Cl. and was prepared as typically illustrated under Example 1(a) above. In the preparation of Polymer IV, the procedure described under Example 7 herein was followed and the B reactant was also derived by the platinumcatalyzed hydrosilation of the abovedescribed Polyether A with H-Si(CH Cl. The reactants, amounts thereof and the relative proportions of the A and C units per mole of B units present in the polymer products are given in the following Table 1.

TABLE 1 Preparation No. l 2 3 4 Polymer No. *1 *11 *111 *lV Reactants Si(OC,H,.)

grams 166.7 333.3 333.3 31.2 mole 0.8 1.6 1.6 0.15

-(C2H4 )d' 3 s' :i]2

W CH CH CH C H CH l'CH CO Molecular Weight 483.6 483.6 483.6 534.5 Average Value of d 7.2 7.2 7.2 6.6 grams 120.9 96.7 48.3 160.4 mole 0.25 0.20 0.1 0.3

(CH,),SiCl

grams 81.39 86.8 97.65 7.1 mole 0.75 0.8 0.9 0075 Water, rams 37.2 73.26 73.26 9.7 Xylene lvent, ml. 200 500 500 Polymer Product Weight, grams 214.0 227 217 Mole Ratio of Units. a;b:c ll/ 3 21113.0 8.0: 124.0 161119 (15111025 Not a polymer of the invention.

ll/ Designates the mole ratio of the SiO IWOlC,l-l O),,-C,H,,Si((ll-l,),O L(CH,),,SiO units, respectively. based on the relative molar proportions of reactants employed.

EXAMPLES -18 In these examples, foams were produced using the above-described Surfactants A through H and .l of the present invention as the respective foam-stabilizing surfactant component of the foam-producing reaction mixture, designated herein as Foam Formulation A, which had the following composition:

TABLE 11 FOAM FORMULATlON A COMPONENT PARTS BY WEIGHT Surfactant Varied (0.35, 0.5 and 1) Polyester polyol Ill 100 N-ethylmorpholine Hexadecyldirnethylamine Water Tolylene diisocyanate 4 (Index 105) {2/ Tris(2-chloroethyl)phosphate 7.

Ill The polyester polyol employed was a commercially available polyester resin produced from adipic acid, diethylene glycol and trimcthylolpropanc in a mole ratio of approximately 111:0.2. This polycster has a hydroxyl number of about 50 to 56. a molecular weight of about 2.000, an acid number not greater than 2 and a viscosity of about 17.000 centistokes at about C. This particular polyester is sold under the name Witco Fomrez No. 50''.

/2/ This component was a mixture of the 2,4 and 2.6-isomers of tolylenc diisocyanate present in a weight ratio of 80:20. respectively. Index 105 designates that the amount of mixture employed was 105 weight per cent of the stoichiometric amount required to react with total reactive hydrogens from the polyester polyol and water present in the foam formulation.

The runs of Examples 10-18 were carried out in accordance with substantially the same general procedure which entailed the following steps. The foam stabilizing surfactant. amine catalysts and water were premixed in a four-ounce capacity jar. The polyester polyol reactant was weighed into a tared container. The flame-retardant [tris(2-chloroethyl)phosphate] and tolylene diisocyanate reactant were also weighed into the container and mixed with a spatula. Further mixing of the polyol, flame-retardant and diisocyanate was done in a drill press equipped with a double threebladed marine-type propellor about 2 inches in diameter and having a 45 pitch. The mixing in the drill press was accomplished at 1,000 revolutions per minute for 8 seconds. Then the premixture of surfactant, catalyst and water was added and mixing was continued for seven additional seconds. The reaction mixture was poured into a cardboard box (12 X 12 X 12 inches), allowed to rise and was then cured for about 30 minutes at C. In most instances, samples were prepared for breathability and flammability measurements.

The following terms are used to describe the quality of the foams produced in the examples:

Rise" denotes the foam height and is directly proportional to potency of the surfactant.

Breathability" denotes the porosity of a foam, being roughly proportional to the number of open cells in a foam, and was measured in accordance with the NOPCO breathability test procedure described by R. E. Jones and G. Fesman, Journal of Cellular Plastics. January, 1965. In accordance with this test, breathability is measured as follows: A piece of foam (1 X 2 X 2 inches) is cut from near the center of the bun. Using a Nopco Foam Breathability Tester, Type GP-2 Model 40GD10, air is drawn through the l-inch portion at a pressure differential of 0.5 inches of water less than atmospheric pressure. The air flow is parallel to direction of original foam rise. The degree of openness of the foam (or foam breathability) is measured by air flow and is expressed as standard cubic feet per minute (SCF M).

Burning Extent" denotes the burned length of a test specimen of foam as measured in accordance with standard flammability test procedure ASTM 1692-57T.

SE" indicates that, on the basis of the results obtained in the aforesaid flammability test. the foam is rated as self-extinguishing.

B indicates that on the basis of the aforesaid flammability test, the sample of foam did not qualify as selfextinguishing and was thus assigned a *burning" (B) rating.

The results based on the use of Surfactants A, B and C at three different concentrations are given in the following Table lll as Examples 10-12, the polyoxyethylene chains of Surfactants A-C being capped with methyl groups. Table 111 also sets forth data (Run Nos. l-lll) obtained using the above-described comparative 3 ,8 8 7,60 l 37 38 Polymers I, ll and Ill the polyether chains of which Surfactant A provided a burner" when used in a conwere also methyl-capped. in comparative Runs l-Ill, centration of one part per 100 parts of polyester polyol, Foam Formulation A and the above-described foaming it allowed for the formation of self-extinguishing foams procedure were also employed. when used at the lower concentrations.

TABLE III Stabilization of Flexible Polyester Foam Using Surfactants Containing SiO CH;,()(C,H O),,C,,H ,Si(CH;,),O,, and (CH i siO units in the mole ratio (a:b:c) indicated below. and wherein the average value of d is 7.2 (Surfactants A. B and Polymers H) or 6.3 (Surfactant C).

Surfactant Foam Properties Parts by Wt. Burning in Foam Rise Breathability Extent Flame No. Designation azbrc Formulation A (inches) (SCFM) (inches) Rating Example AAA BBB

SE SE SE CCC Polymer Run.No.

8.0:l:4.0 1.0 Collapse *lll |6:l:9 L0 Collapse The results obtained in Examples 13-l8 in which Surfactants D through H and .l were used are presented polyester-based urethane in the following Table [V which also sets-forth data o y ers I, H and fi fl (Run No. IV) obtained using the above-described comthis purpose. In addition to having good parative Polymer IV as the surfactant component of Foam Formulation A. The polyoxyethylene chains of possess the Surfactants D-H and J and of Polymer IV were capped formation of with benzyl or a combination of benzyl and acetyl Although groups, as above described.

TABLE IV Stabilization of Flexible Polyester Foam Using Surfactants Containing SiO WO(C,H.O) C,H.Si(CH;) O and (CH hSiO units in the mole ratio (a:b:c) given below. and wherein WO- is either benzyloxy or acetoxy and the average value ofd is about 6.3 or 6.6.

Surfactant Foam Properties Parts by Wt. Burning in Foam Rise Breathability Extent Flame No. Designation a;b:c Formulation A (inches) (SCFM) (inches) Rating The data of Examples -12 of Table I show that Surfactants A, B and C of the present invention are effective stabilizers of flexible foams. On the other hand ineffective for Example Not a polymer of the invention.

potency as foam stabilizers, the results of Table lll also show that. overall, Surfactants A. B and C further desirable property of allowing for self-extinguishing, flame-retarded foams.

DDD

SE SE PFC.

polyoxyethylcnc chains is C,H,,CH and the average value of d is about 6.3.

and the average value of d is about on Polymer lV *lV 

1. AN ORGANOSILICONE POLYMER WHICH CONSISTS ESSENTIALLY OF MONOMERIC UNITS (A), (B) AND (C) WHEREIN: (A) IS SIO4/2; (B) IS A MONOFUNCTIONAL SILOXY UNIT HAVING THE UNIT FORMULA,
 1. An organosilicone polymer which consists essentially of monomeric units (A), (B) and (C) wherein: (A) is SiO4/2; (B) is a monofunctional siloxy unit having the unit formula,
 2. The organosilicone polymer of claim 1 in which the (B) units consist essentially of those in which e has a value of one and f has a value of two.
 3. The organosilicone polymer of claim 2 in which said R group has from 1 to 12 carbon atoms.
 4. The organosilicone polymer of claim 1 in which the (B) units consist essentially of those in which e has a value of two and f has a value of one.
 5. The organosilicone polymer of claim 1 in which the (B) units consist essentially of those in which e has a value of three.
 6. The organosilicone polymer of claim 1 in which (C) has the unit formula, R*3SiO1/2, wherein R* is a monovalent hydrocarbon group having from 1 to 12 carbon atoms.
 7. An organosilicone polymer which consists essentially of monomeric units (A), (B) and (C) where: (A) is SiO4/2; (B) is a monofunctional unit having the formula,
 8. The polymer of claim 7 wherein said monovalent hydrocarbon groups, R and R*, are lower alkyl groups.
 9. An organosilicon polymer which consists essentially of monomeric: units (A), (B) and (C) where (A) is SiO4/2, (B) is a monofunctional siloxy unit having the formula,
 10. The polymer of claim 9 in which R**is a lower alkyl radical.
 11. The polymer of claim 10 in which R**is a methyl group.
 12. The polymer of claim 9 in which R**is an aralkyl radical.
 13. The polymer of claim 12 in which R**is a benzyl group.
 14. An organosilicone polymer which consists essentially of monomeric units (A), (B) and (C) wherein: (A) is SiO4/2; (B) is a monofunctional siloxy unit having the formula,
 15. The polymer of claim 14 in which W is said monovalent hydrocarbon radical, R**.
 16. The polymer of claim 15 in which R**is a lower alkyl radical.
 17. The polymer of claim 16 in which said alkyl radical is methyl.
 18. The polymer of claim 15 in which R**is an aryl group.
 19. The polymer of claim 18 in which said aryl group is phenyl.
 20. The polymer of claim 15 in which R**is an aralkyl group.
 21. The polymer of claim 20 in which said aralkyl group is benzyl.
 22. The polymer of claim 14 in which W is said R**C(O)- group.
 23. The polymer of claim 22 in which R** of said R**C(O)- group is methyl.
 24. The polymer of claim 14 in which W is said R**NHC(O)- group.
 25. The polymer of claim 24 in which R** of said R**NHC(O)-group is methyl. 